Polyethylene wax
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Polyethylene Wax Properties

Polyethylene wax is a low-molecular-weight polyethylene used as a versatile additive across plastics, coatings, inks, cosmetics, and adhesives. It is a high-performance synthetic wax widely used across industries for its excellent thermal stability, lubrication properties, and compatibility with polymers. Because of its polyolefin backbone, PE wax offers a unique blend of lubrication, gloss, and compatibility with nonpolar systems. Whether you're formulating masterbatches, coatings, adhesives, or PVC compounds, understanding the physical and chemical properties of PE wax is essential for optimising product performance.

In this blog, we cover essential information about polyethylene wax, including PE wax melting point, PE wax density, PE wax chemical density, PE wax viscosity, uses of polyethylene wax, and PE wax physical properties, to help formulators select the right grade for their applications.

Properties of Polyethylene Wax

Polyethylene wax is a solid, wax-like polymer derived from ethylene. It is non-polar and hydrophobic, and it blends well with other hydrocarbon systems. Its compatibility depends on molecular weight and crystallinity. PE wax typically appears as a white or off-white, odourless solid at room temperature. It melts and flows when heated, enabling easy incorporation into blends, emulsions, and coatings.

Its defining properties include:

  • High melting point
  • Low viscosity
  • Excellent hardness and abrasion resistance
  • Chemical inertness
  • Thermal stability

These attributes make PE wax ideal for high-temperature processing and demanding industrial environments.

PE Wax Melting Point

The melting point of polyethylene wax typically ranges from 100°C to 140°C. It is influenced by grade, molecular weight, and crystallinity. Higher melting points are preferred in applications requiring thermal resistance, such as:

  • Hot melt adhesives
  • Powder coatings
  • PVC extrusion

The melting point helps determine how PE wax behaves as a lubricant, slip agent, or mold-release additive during processing. It also affects storage stability and performance in hot-mill or extrusion processes.

PE Wax Density

PE wax density (paraffin wax) is often cited for comparison, since many wax applications involve both PE and paraffin grades. Paraffin wax densities (physical density) typically range from 0.92 to 0.98 g/cm³ at room temperature, depending on crystallinity, refinement, grade and molecular structure.

While paraffin and polyethylene waxes share a waxy, solid state, their densities reflect different hydrocarbon backbones (paraffin being a more saturated, straight-chain hydrocarbon mix, PE wax being a low-molecular-weight polyolefin). Understanding PW wax density helps formulators predict phase behaviour when blending with PE wax.

Higher-density PE waxes tend to offer better mechanical strength and gloss in coatings and films.

PE Wax Chemical Density

Chemical density, as a concept for waxes, is not a standard specification. Still, the phrase "PE wax chemical density" can be interpreted as the material’s chemical characteristics that influence density and compatibility. The chemical density of PE wax reflects molecular packing and hydrocarbon chain structure, which influence compatibility with other polymers and solvents.

PE wax is non-polar with a hydrocarbon backbone. This non-polarity yields low surface energy and good compatibility with nonpolar systems, but limited miscibility with polar components (such as water, certain pigments, or hydrophilic resins).

The non-polar, hydrocarbon nature of PE wax gives it excellent chemical resistance to many oils and solvents at room temperature. Still, it requires compatibilisers or surfactants for dispersing in polar matrices or aqueous emulsions.

PE Wax Viscosity

Viscosity is highly temperature-dependent. At processing temperatures, PE wax demonstrates a wide viscosity range depending on molecular weight and degree of crystallinity. PE wax typically exhibits low melt viscosity, ranging from 10 to 500 mPa·s at processing temperatures. This allows for:

  • Smooth dispersion in polymer matrices
  • Improved flow in extrusion and injection molding
  • Enhanced surface levelling in coatings

Viscosity varies with molecular weight and temperature, so selecting the right grade is critical for process optimisation. For extrusion, coating, or ink applications, adjusting temperature, shear, and additive packages will tailor the viscosity to achieve desired slurry stability, film formation, and slip properties.

Uses of Polyethylene Wax

Polyethylene wax is used in a wide range of industrial applications. Its versatility and compatibility with other waxes and polymers make it a staple in formulation design. Its uses include:

  1. Plastics processing and additives: PE wax is widely used as a lubricant, slip agent, and mold-release additive in polymer processing, including extrusion, injection molding, and wire and cable processing.
  2. Coatings and inks: It improves slip, gloss, mar resistance, and block resistance. It can act as a polishing agent in surface coatings and as a release agent in packaging coatings.
  3. Cosmetics and personal care: PE wax is used as a thickener, texture enhancer, and gloss agent in lip balms, creams, and moisturisers.
  4. Adhesives and paper products: It serves as a toughening additive, anti-block agent, and dispersant in pressure-sensitive adhesives and in paper coatings and wax emulsions.
  5. Rubber and asphalt: In some formulations, PE wax acts as a processing aid or modifier to improve low-temperature performance and processability. It can also be used to modify asphalt binders for improved workability and performance.

The uses of polyethylene wax span industrial processing, consumer packaging, and cosmetic applications, reflecting its balance of heat stability, non-polar compatibility, and lubricating properties.

Physical Properties of PE Wax

PE wax is a low-molecular-weight polyethylene with a non-polar hydrocarbon structure. The specific grade and processing history influence its density and crystalline fraction.

Key physical properties of polyethylene wax include:

  • Appearance: White, odourless flakes, beads, or powder
  • Hardness: High, with excellent abrasion resistance
  • Solubility: Insoluble in water; soluble in aromatic and aliphatic hydrocarbons
  • Thermal stability: Maintains integrity under high shear and temperature
  • Polarity: Non-polar, making it compatible with polyolefins

These properties contribute to its performance in surface protection, lubrication, and dispersion systems.

Wrap-up:

The properties of polyethylene wax make it a versatile component for a broad range of applications. Its relatively low melting point, non-polar chemistry, and lubrication characteristics enable effective use as a processing aid, slip agent, mold-release additive, and performance modifier in coatings, inks, cosmetics, and adhesives.

Understanding PE wax melting point, density, viscosity, and physical properties empowers formulators to select the right grade for their specific application. Whether you're enhancing gloss in coatings, improving flow in plastics, or stabilising adhesives, PE wax delivers consistent performance under thermal and mechanical conditions.

As industries continue to demand scalable, high-performance materials, polyethylene wax remains a reliable, cost-effective solution.

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